A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the axioms. First the Boltzmann–Planck formula is derived. Building on this formula, using the Law of Large Numbers—a basic theorem of probability theory—the von Neumann formula is deduced. Axioms used in older theories on the foundations are now derived facts.

Foundational issues in statistical mechanics and the more general question of how probability is to be understood in the context of physical theories are both areas that have been neglected by philosophers of physics. This book fills an important gap in the literature by providing a most systematic study of how to interpret probabilistic assertions in the context of statistical mechanics. The book explores both subjectivist and objectivist accounts of probability, and takes full measure of work in (...) the foundations of probability theory, in statistical mechanics, and in mathematical theory. It will be of particular interest to philosophers of science, physicists and mathematicians interested in foundational issues, and also to historians of science. (shrink)

Equilibrium states are used as limit states to define thermodynamically reversible processes. When these processes are implemented in statistical physics, these limit states become unstable and can change with time, due to thermal fluctuations. For macroscopic systems, the changes are insignificant on ordinary time scales and what little there is can be suppressed by macroscopically negligible, entropy-creating dissipation. For systems of molecular sizes, the changes are large on short time scales and can only sometimes be suppressed with significant (...) entropy-creating dissipation. As a result, at molecular scales, thermodynamically reversible processes are impossible in principle, even as approximations, when we account for all sources of dissipation. (shrink)

Roughly speaking, classical statistical physics is the branch of theoretical physics that aims to account for the thermal behaviour of macroscopic bodies in terms of a classical mechanical model of their microscopic constituents, with the help of probabilistic assumptions. In the last century and a half, a fair number of approaches have been developed to meet this aim. This study of their foundations assesses their coherence and analyzes the motivations for their basic assumptions, and the interpretations of (...) their central concepts. The most outstanding foundational problems are the explanation of time-asymmetry in thermal behaviour, the relative autonomy of thermal phenomena from their microscopic underpinning, and the meaning of probability. A more or less historic survey is given of the work of Maxwell, Boltzmann and Gibbs in statistical physics, and the problems and objections to which their work gave rise. Next, we review some modern approaches to (i) equilibrium statistical mechanics, such as ergodic theory and the theory of the thermodynamic limit; and to (ii) non-equilibrium statistical mechanics as provided by Lanford's work on the Boltzmann equation, the so-called Bogolyubov-Born-Green-Kirkwood-Yvon approach, and stochastic approaches such as `coarse-graining' and the `open systems' approach. In all cases, we focus on the subtle interplay between probabilistic assumptions, dynamical assumptions, initial conditions and other ingredients used in these approaches. (shrink)

Statistical physicists assume a probability distribution over micro-states to explain thermodynamic behavior. The question of this paper is whether these probabilities are part of a best system and can thus be interpreted as Humean chances. I consider two Boltzmannian accounts of the Second Law, viz. a globalist and a localist one. In both cases, the probabilities fail to be chances because they have rivals that are roughly equally good. I conclude with the diagnosis that well-defined micro-probabilities under-estimate the robust (...) character of explanations in statistical physics. (shrink)

After the birth of thermodynamics’ second principle—outlined in Carnot's Réflexions sur la puissance motrice du feu —several studies provided new arguments in the field. Mainly, they concerned the thermodynamics’ first principle—including energy conceptualisation—, the analytical aspects of the heat propagation, the statistical aspects of the mechanical theory of heat. In other words, the second half of nineteenth century was marked by an intense interdisciplinary research activity between physics and chemistry: new disciplines applied to the heat developed in the (...) form of analytical, mechanical and statistical theories. Inside all these theories, entropy—the brand-new function that Clausius coined in his Mechanical theory of heat—started to play a central epistemic role. In the present paper, we analyse some steps of the historical process of conceptualisation of such function from 1850 to 1902. Particularly, we retrace the historical–foundational path that—starting from Clausius’ Second Law—lead Boltzmann and Gibbs to their distinguished formulations of statistical entropy. As usual, our research has been unrolled through the analyses of primary sources and by leaning on critical readings of the secondary literature. As for the methodological approach, text analysis of historical documents constituted our privileged modus operandi. This paper is the expression of a collaborative historical research program focused on the thermodynamic foundations of physics–chemistry relationship; early results have already been published by the same authors upon the concepts of reversibility––and––thermal equilibrium. (shrink)

An important contribution to the foundations of probability theory, statistics and statistical physics has been made by E. T. Jaynes. The recent publication of his collected works provides an appropriate opportunity to attempt an assessment of this contribution.

In an illuminating article, Claus Beisbart argues that the recently-popular thesis that the probabilities of statistical mechanics (SM) are Best System chances runs into a serious obstacle: there is no one axiomatization of SM that is robustly best, as judged by the theoretical virtues of simplicity, strength, and fit. Beisbart takes this 'no clear winner' result to imply that the probabilities yielded by the competing axiomatizations simply fail to count as Best System chances. In this reply, we express sympathy (...) for the 'no clear winner' thesis. However, we argue that an importantly different moral should be drawn from this. We contend that the implication for Humean chances is not that there are no SM chances, but rather that SM chances fail to be sharp. (shrink)

In a pair of articles and in his recent book, Miklos Redei has taken enormous strides toward characterizing the conditions under which relativistic quantum field theory is a safe setting for the deployment of causal talk. Here, we challenge the adequacy of the accounts of causal dependence and screening off on which rests the relevance of Redei's theorems to the question of causal good behavior in the theory.

Foundational issues in statistical mechanics and the more general question of how probability is to be understood in the context of physical theories are both areas that have been neglected by philosophers of physics. This book fills an important gap in the literature by providing a most systematic study of how to interpret probabilistic assertions in the context of statistical mechanics. The book explores both subjectivist and objectivist accounts of probability, and takes full measure of work in (...) the foundations of probability theory, in statistical mechanics, and in mathematical theory. It will be of particular interest to philosophers of science, physicists and mathematicians interested in foundational issues, and also to historians of science. (shrink)

Constantin Caratheodory offered the first systematic and contradiction free formulation of thermodynamics on the basis of his mathematical work on Pfaff forms. Moreover, his work on measure theory provided the basis for later improved formulations of thermodynamics and physics of continua where extensive variables are measures and intensive variables are densities. Caratheodory was the first to see that measure theory and not topology is the natural tool to understand the difficulties (ergodicity, approach to equilibrium, irreversibility) in the Foundations of (...) Statistical Physics. He gave a measure-theoretic proof of Poincaré's recurrence theorem in 1919. This work paved the way for Birkhoff to identify later ergodicity as metric transitivity and for Koopman and von Neumann to introduce spectral analysis of dynamical systems in Hilbert spaces. Mixing provided an explanation of the approach to equilibrium but not of irreversibility. The recent extension of spectral theory of dynamical systems to locally convex spaces, achieved by the Brussels–Austin groups, gives new nontrivial time asymmetric spectral decompositions for unstable and/or non-integrable systems. In this way irreversibility is resolved in a natural way. (shrink)

Statistical mechanics is one of the crucial fundamental theories of physics, and in his new book Lawrence Sklar, one of the pre-eminent philosophers of physics, offers a comprehensive, non-technical introduction to that theory and to attempts to understand its foundational elements. Among the topics treated in detail are: probability and statistical explanation, the basic issues in both equilibrium and non-equilibrium statistical mechanics, the role of cosmology, the reduction of thermodynamics to statistical mechanics, and the (...) alleged foundation of the very notion of time asymmetry in the entropic asymmetry of systems in time. The book emphasises the interaction of scientific and philosophical modes of reasoning, and in this way will interest all philosophers of science as well as those in physics and chemistry concerned with philosophical questions. The book could also be read by an informed general reader interested in the foundations of modern science. (shrink)

The positions Ross & Spurrett (R&S) take on issues of information, causality, functionalism, and emergence are actually implicit in the theory and practice of statistical physics, specifically in the way it relates macroscopic collective coordinates to microscopic physics. The reasons for taking macroscopic physical variables like temperature or magnetization to be real apply equally to mental properties like pain.

Review article of Y.M. Guttmann, <em>The Concept of Probability in Statistical Physics</em>, Cambridge: Cambridge University Press, 1999.

An important contribution to the foundations of probability theory, statistics and statistical physics has been made by E. T. Jaynes. The recent publication of his collected works provides an appropriate opportunity to attempt an assessment of this contribution.

I. Prigogine has proposed, and the writings of N. S. Krylov to some extent suggest, a novel and unorthodox solution to foundational problems in statistical mechanics. In particular, the view claims to offer new insight into two interconnected problems: understanding the role of probability in physics, and that of reconciling the irreversibility of physical processes with the temporal symmetry of dynamical theories. The approach in question advocates a conception of the state of a system which incorporates features of (...) the quantum mechanical state concept in a context, classical statistical mechanics, where quantum considerations are generally considered to be irrelevant. I examine the plausibility of this new approach by offering an analysis of the various notions of state employed in modern physics. ;In the first chapter, I analyze the conceptual connections between dynamical laws and the nature of a system's state. I argue that laws and states are correlative. In constructing dynamical theories one does not start with a fixed or pre-determined state concept. Neither is one given the laws of the theory from which the conception of state is derived. Rather, we get the law/state structure as a "package." In light of this general analysis, I next examine the notion of state employed in the quantum theory. Here I consider a variety of conceptions of quantum states and assess their ability to answer the "paradoxes" of quantum theory. I pay particular attention to the role of probability and related restrictions on the realization of certain states. The new approach to statistical mechanics proposes to exploit similar restrictions on states in order to resolve the irreversibility problem. But is this unorthodox approach viable? In the final four chapters, I offer a detailed critique of this approach, examining the plausibility of the radical reworking of the state concept. I argue that while some important progress can be made, certain old puzzles remain, and new and difficult ones arise--ones which raise serious doubts about the ultimate success of this particular approach. I conclude, however, by arguing that such radical proposals are not unmotivated; and that novel and unorthodox proposals concerning the foundations of statistical mechanics must be taken seriously. (shrink)

Much research on cognitive development focuses either on early-emerging domain-specific knowledge or domain-general learning mechanisms. However, little research examines how these sources of knowledge interact. Previous research suggests that young infants can make inferences from samples to populations (Xu & Garcia, 2008) and 11- to 12.5-month-old infants can integrate psychological and physical knowledge in probabilistic reasoning (Teglas, Girotto, Gonzalez, & Bonatti, 2007; Xu & Denison, 2009). Here, we ask whether infants can integrate a physical constraint of immobility into a (...) class='Hi'>statistical inference mechanism. Results from three experiments suggest that, first, infants were able to use domain-specific knowledge to override statistical information, reasoning that sometimes a physical constraint is more informative than probabilistic information. Second, we provide the first evidence that infants are capable of applying domain-specific knowledge in probabilistic reasoning by using a physical constraint to exclude one set of objects while computing probabilities over the remaining sets. (shrink)

This textbook carefully develops the main ideas and techniques of statistical and thermal physics and is intended for upper-level undergraduate courses. The authors each have more than thirty years' experience in teaching, curriculum development, and research in statistical and computational physics. Statistical and Thermal Physics begins with a qualitative discussion of the relation between the macroscopic and microscopic worlds and incorporates computer simulations throughout the book to provide concrete examples of important conceptual ideas. Unlike (...) many contemporary texts on thermal physics, this book presents thermodynamic reasoning as an independent way of thinking about macroscopic systems. Probability concepts and techniques are introduced, including topics that are useful for understanding how probability and statistics are used. Magnetism and the Ising model are considered in greater depth than in most undergraduate texts, and ideal quantum gases are treated within a uniform framework. Advanced chapters on fluids and critical phenomena are appropriate for motivated undergraduates and beginning graduate students. Integrates Monte Carlo and molecular dynamics simulations as well as other numerical techniques throughout the text Provides self-contained introductions to thermodynamics and statistical mechanics Discusses probability concepts and methods in detail Contains ideas and methods from contemporary research Includes advanced chapters that provide a natural bridge to graduate study Features more than 400 problems Programs are open source and available in an executable cross-platform format Solutions manual. (shrink)

The recent discovery of a Higgs boson prompted increased attention of statisticians and philosophers of science to the statistical methodology of High Energy Physics. Amidst long-standing debates within the field, HEP has adopted a mixed statistical methodology drawing upon both frequentist and Bayesian methods, but with standard frequentist techniques such as significance testing and confidence interval estimation playing a primary role. Physicists within HEP typically deny that their methodological decisions are guided by philosophical convictions, but are instead (...) based on “pragmatic” considerations, thus distancing themselves from what they perhaps perceive as an ongoing pitched ideological battle between frequentists and Bayesians. Here I argue that there is a philosophical orientation to HEP that is neither exclusively frequentist nor Bayesian, but that lies squarely in the tradition of philosophical pragmatism. I further argue that understanding the statistical methodology of HEP through the perspective of pragmatism clarifies the role of and rationale for significance testing in the search for new phenomena such as the Higgs boson. (shrink)

Amidst long-running debates within the field, high energy physics has adopted a statistical methodology that primarily employs standard frequentist techniques such as significance testing and confidence interval estimation, but incorporates Bayesian methods for limited purposes. The discovery of the Higgs boson has drawn increased attention to the statistical methods employed within HEP. Here I argue that the warrant for the practice in HEP of relying primarily on frequentist methods can best be understood as pragmatic, in the sense (...) that statistical methods are chosen for their suitability for the practical demands of experimental HEP, rather than reflecting a commitment to a particular epistemic framework. In particular, I argue that understanding the statistical methodology of HEP through the perspective of pragmatism clarifies the role of and rationale for significance testing in the search for new phenomena such as the Higgs boson. (shrink)

The statistical aspects of quantum explanation are intrinsic to quantum physics; individual quantum events are created in the interactions associated with observation and are not describable by predictive theory. The superposition principle shows the essential difference between quantum and non-quantum physics, and the principle is exemplified in the classic single-photon two-slit interference experiment. Recently Mandel and Pfleegor have done an experiment somewhat similar to the optical single-photon experiment but with two independently operated lasers; interference is obtained even (...) with beam intensity so small that only one photon is in the apparatus at a time. The result can be understood in terms of the superposition of states; or, in terms of the Uncertainty Principle, which is found to forbid the determination of which of the two lasers is the source of a given photon (if conditions for interference are to obtain). The Mandel-Pfleegor experiment gives a physical argument against the continuous localization of a photon that is assumed in the hidden variable theories and therefore gives further support for the generally accepted view that an observed entity (observed state) is created in the observation event. This aspect of quantum physics implies a subjectivism on the level of individual quantum-level occurrences, since there is in quantum theory no basis for asserting the existence of the event independently of observation of it. Extension of this subjectivism to large scale, non-quantum phenomena falls within the principles of quantum theory; counter considerations that argue against such an extension are noted. (shrink)

This study examined the effect of a prior bout of exercise on implicit cognition. Specifically, we examined whether a prior bout of moderate intensity exercise affected performance on a statistical learning task in healthy adults. A total of 42 participants were allocated to one of three conditions—a control group, a group that exercised for 15 min prior to the statistical learning task, and a group that exercised for 30 min prior to the statistical learning task. The participants (...) in the exercise groups cycled at 60% of their respective V˙O2max. Each group demonstrated significant statistical learning, with similar levels of learning among the three groups. Contrary to previous research that has shown that a prior bout of exercise can affect performance on explicit cognitive tasks, the results of the current study suggest that the physiological stress induced by moderate-intensity exercise does not affect implicit cognition as measured by statistical learning. (shrink)

This paper is a preliminary exploration of the connections between the statistical style of reasoning and the research practices of statistical mechanics in the early period of the long quantum revolution. It suggests that before 1925 the instantiations of the statistical style in physics went through two phases. The first phase consisted of the formulation of the Maxwell‐Boltzmann statistics on the basis of the population‐gas analogy. The second phase was characterized by the generalization of the Maxwell‐Boltzmann (...) statistics through analogies between ideal gas molecules and other microphysical entities, analogies that shaped and were shaped by the rise of quantum theory. Einstein's invention of the Bose‐Einstein statistics started a third phase and created the conditions of possibility for a new classification of microphysical entities according to their different statistics. (shrink)

Bell’s theorem is often said to imply that quantum mechanics violates local causality, and that local causality cannot be restored with a hidden-variables theory. This however is only correct if the hidden-variables theory fulfils an assumption called Statistical Independence. Violations of Statistical Independence are commonly interpreted as correlations between the measurement settings and the hidden variables. Such correlations have been discarded as “fine-tuning” or a “conspiracy”. We here point out that the common interpretation is at best physically ambiguous (...) and at worst incorrect. The problem with the common interpretation is that Statistical Independence might be violated because of a non-trivial measure in state space, a possibility we propose to call “supermeasured”. We use Invariant Set Theory as an example of a supermeasured theory that violates the Statistical Independence assumption in Bell’s theorem without requiring correlations between hidden variables and measurement settings. (shrink)

I review the role of probability in contemporary physics and the origin of probabilistic time asymmetry, beginning with the pre-quantum case but concentrating on quantum theory. I argue that quantum mechanics radically changes the pre-quantum situation and that the philosophical nature of objective probability in physics, and of probabilistic asymmetry in time, is dependent on the correct resolution of the quantum measurement problem.

Spin-statistics transmutation is the phenomenon occurring when a “dressing” transformation introduced for physical reasons (e.g. gauge invariance) modifies the “bare” spin and statistics of particles or fields. Historically, it first appeared in Quantum Mechanics and in semiclassical approximation to Quantum Field Theory. After a brief historical introduction, we sketch how to describe such phenomenon in Quantum Field Theory beyond the semiclassical approximation, using a path-integral formulation of euclidean correlation functions, exemplifying with anyons, dyons and skyrmions.