Entropy is ubiquitous in physics, and it plays important roles in numerous other disciplines ranging from logic and statistics to biology and economics. However, a closer look reveals a complicated picture: entropy is defined differently in different contexts, and even within the same domain different notions of entropy are at work. Some of these are defined in terms of probabilities, others are not. The aim of this chapter is to arrive at an understanding of some of the (...) most important notions of entropy and to clarify the relations between them, After setting the stage by introducing the thermodynamic entropy, we discuss notions of entropy in information theory, statistical mechanics, dynamical systems theory and fractal geometry. (shrink)

Daniel R. Brooks and E. O. Wiley have proposed a theory of evolution in which fitness is merely a rate determining factor. Evolution is driven by non-equilibrium processes which increase the entropy and information content of species together. Evolution can occur without environmental selection, since increased complexity and organization result from the likely capture at the species level of random variations produced at the chemical level. Speciation can occur as the result of variation within the species which decreases the (...) probability of sharing genetic information. Critics of the Brooks-Wiley theory argue that they have abused terminology from information theory and t thermodynamics. In this paper I review the essentials of the theory, and give an account of hierarchical physical information systems within which the theory can be interpreted. I then show how the major conceptual objections can be answered. (shrink)

I assess the thesis that counterfactual asymmetries are explained by an asymmetry of the global entropy at the temporal boundaries of the universe by developing a new semantic element for counterfactuals called objective assertibility and a method of evaluating counterfactuals that constrains consideration to possibilities where the early universe has low entropy. The resulting theory vindicates the common practice of holding the past mostly fixed under counterfactual supposition while at the same time allowing the counterfactual's antecedent to obtain (...) by a natural physical development. While excellent for evaluating a wide variety of ordinary counterfactuals, it does not fully succeed as an explanation of counterfactual asymmetry. (shrink)

Disagreements over the meaning of the thermodynamic entropy and how it should be defined in statistical mechanics have endured for well over a century. In an earlier paper, I showed that there were at least nine essential properties of entropy that are still under dispute among experts. In this paper, I examine the consequences of differing definitions of the thermodynamic entropy of macroscopic systems.Two proposed definitions of entropy in classical statistical mechanics are (1) defining entropy (...) on the basis of probability theory (first suggested by Boltzmann in 1877), and (2) the traditional textbook definition in terms of a volume in phase space (also attributed to Boltzmann). The present paper demonstrates the consequences of each of these proposed definitions of entropy and argues in favor of a definition based on probabilities. (shrink)

Entropy and information are both emerging as currencies of interdisciplinary dialogue, most recently in evolutionary theory. If this dialogue is to be fruitful, there must be general agreement about the meaning of these terms. That this is not presently the case owes principally to the supposition of many information theorists that information theory has succeeded in generalizing the entropy concept. The present paper will consider the merits of the generalization thesis, and make some suggestions for restricting both (...) class='Hi'>entropy and information to specific arenas of discourse. (shrink)

This book is about an important issue which has arisen within two of the branches of physical science - namely thermodynamics and statistical mechanics - where the notion of entropy plays an essential role. A number of scientists and information theorists have maintained that entropy is a subjective concept and is a measure of human ignorance. Such a view, if it is valid, would create some profound philosophical problems and would tend to undermine the objectivity of the scientific (...) enterprise. Whilst the present volume is not a treatise on thermodynamics or statistical mechanics, all relevant steps in the building up of these disciplines are carefully scrutinised and it is concluded that the charge of subjectivity cannot be upheld. The widely adopted view that entropy is a measure of disorder, or of lack of information, is shown to be ambiguous, although it may be of use in certain contexts. (shrink)

The major global challenges of our time, like climate and environmental crises, rising inequality, the emergence of disruptive technologies, etc., demand interdisciplinary research for effective solutions. A clear understanding of value is essential for guiding socio-cultural and economic transitions to address these issues. Despite numerous attempts to define value, existing approaches remain inconsistent across disciplines and lack a comprehensive framework. This paper introduces a novel perspective on value through the lens of granular interaction thinking theory, proposing an informational entropy-based (...) notion of value. Grounded on quantum mechanics, Shannon’s information theory, and the mindsponge theory, this framework integrates both subjective and objective considerations and is highly compatible with interdisciplinary research. The informational entropy-based notion of value effectively bridges diverse concepts of value, including use and exchange value in economics, personal values in psychology, and cultural, moral, ethical, and aesthetic values in society. By offering a unifying perspective, granular interaction thinking theory provides a valuable framework for translating insights from quantum mechanics into socio-cultural, economic, and psychological contexts, enriching theoretical discourse and enhancing analytical effectiveness. (shrink)

Logical information theory is the quantitative version of the logic of partitions just as logical probability theory is the quantitative version of the dual Boolean logic of subsets. The resulting notion of information is about distinctions, differences and distinguishability and is formalized using the distinctions of a partition. All the definitions of simple, joint, conditional and mutual entropy of Shannon information theory are derived by a uniform transformation from the corresponding definitions at the logical level. The purpose of this (...) paper is to give the direct generalization to quantum logical information theory that similarly focuses on the pairs of eigenstates distinguished by an observable, i.e., qudits of an observable. The fundamental theorem for quantum logical entropy and measurement establishes a direct quantitative connection between the increase in quantum logical entropy due to a projective measurement and the eigenstates that are distinguished by the measurement. Both the classical and quantum versions of logical entropy have simple interpretations as “two-draw” probabilities for distinctions. The conclusion is that quantum logical entropy is the simple and natural notion of information for quantum information theory focusing on the distinguishing of quantum states. (shrink)

The notion of conditional entropy is extended to noncomposite systems. The \-deformed entropic inequalities, which usually are associated with correlations of the subsystem degrees of freedom in bipartite systems, are found for the noncomposite systems. New entropic inequalities for quantum tomograms of qudit states including the single qudit states are obtained. The Araki–Lieb inequality is found for systems without subsystems.

Using computer simulations, we investigate the time evolution of the (Boltzmann) entropy of a dense fluid not in local equilibrium. The macrovariables M describing the system are the (empirical) particle density f = {f(x,v)} and the total energy E. We find that S(ft,E) is a monotone increasing in time even when its kinetic part is decreasing. We argue that for isolated Hamiltonian systems monotonicity of S(Mt) = S(MXt) should hold generally for ‘‘typical’’ (the overwhelming majority of) initial microstates (phase (...) points) X0 belonging to the initial macrostate M0, satisfying MX0 = M0. This is a consequence of Liouville's theorem when Mt evolves according to an autonomous deterministic law. (shrink)

The Anthropocene crisis is frequently described as the rarefaction of resources or resources per capita. However, both energy and minerals correspond to fundamentally conserved quantities from the perspective of physics. A specific concept is required to understand the rarefaction of available resources. This concept, entropy, pertains to energy and matter configurations and not just to their sheer amount. However, the physics concept of entropy is insufficient to understand biological and social organizations. Biological phenomena display both historicity and systemic (...) properties. A biological organization, the ability of a specific living being to last over time, results from history, expresses itself by systemic properties, and may require generating novelties The concept of anti-entropy stems from the combination of these features. We propose that Anthropocene changes disrupt biological organizations by randomizing them, that is, decreasing anti-entropy. Moreover, second-order disruptions correspond to the decline of the ability to produce functional novelties, that is, to produce anti-entropy. (shrink)

This essay is, primarily, a discussion of four results about the principle of maximizing entropy (MAXENT) and its connections with Bayesian theory. Result 1 provides a restricted equivalence between the two: where the Bayesian model for MAXENT inference uses an "a priori" probability that is uniform, and where all MAXENT constraints are limited to 0-1 expectations for simple indicator-variables. The other three results report on an inability to extend the equivalence beyond these specialized constraints. Result 2 established a sensitivity (...) of MAXENT inference to the choice of the algebra of possibilities even though all empirical constraints imposed on the MAXENT solution are satisfied in each measure space considered. The resulting MAXENT distribution is not invariant over the choice of measure space. Thus, old and familiar problems with the Laplacian principle of Insufficient Reason also plague MAXENT theory. Result 3 builds upon the findings of Friedman and Shimony (1971; 1973) and demonstrates the absence of an exchangeable, Bayesian model for predictive MAXENT distributions when the MAXENT constraints are interpreted according to Jaynes's (1978) prescription for his (1963) Brandeis Dice problem. Lastly, Result 4 generalizes the Friedman and Shimony objection to cross-entropy (Kullback-information) shifts subject to a constraint of a new odds-ratio for two disjoint events. (shrink)

For the first time Entropy has been completely revised and updated to include a new subtitle which reflects the expanded focus on the greenhouse effect--the largest crisis ever to face mankind.

Two open questions of inductive reasoning are solved: (1) does the principle of maximum entropy (pme) give a solution to the obverse Majerník problem; and (2) is Wagner correct when he claims that Jeffrey’s updating principle (jup) contradicts pme? Majerník shows that pme provides unique and plausible marginal probabilities, given conditional probabilities. The obverse problem posed here is whether pme also provides such conditional probabilities, given certain marginal probabilities. The theorem developed to solve the obverse Majerník problem demonstrates that (...) in the special case introduced by Wagner pme does not contradict jup, but elegantly generalizes it and offers a more integrated approach to probability updating. (shrink)

In this paper, we discuss how to conceptual engineer ‘entropy’ and ‘information’ as they are used in information theory or statistical mechanics. Initially, we evaluate the extent to which the all-pervasive entangled use of entropy and information notions can be somehow defective in these domains, such as being meaningless or generating confusion. Then, we assess the main ameliorative strategies to improve this defective conceptual practice. The first strategy is to substitute the terms ‘entropy’ and ‘information’ by non-loaded (...) terms, as it was first argued by Bar-Hillel (1955). A second strategy is to prescribe how these terms should be correctly used to be meaningful, as it was pioneered by Carnap (1952 [1977]) in Two Essays on Entropy. However, the actual implementation of these two ameliorative strategies has been historically unsuccessful due to the low credentials that philosophers as conceptual prescribers have among scientists. Finally, to try to solve these obstacles, we propose a third strategy based on leveraging evidence from the contribution of ‘Philosophy in Science’ (à la Pradeau et al. 2024) to integrate conceptual prescriptions and analyses of entropy and information as part of the scientific practices in which these notions are used. (shrink)

We review some notions for general quantum entropies. The entropy of the compound systems is discussed and a numerical computation of the quantum dynamical systems is carried for the noisy optical channel.

A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the axioms. First the Boltzmann–Planck formula is derived. Building on this formula, using the Law of Large Numbers—a basic theorem of probability theory—the von Neumann formula is deduced. Axioms used in older theories on the foundations are now derived facts.

Both a method of therapy and an exploration of psychic reality, free association is a fundamental element of psychoanalytical practices that refers to the way a patient is asked to describe what comes spontaneously to mind in the therapeutic setting. This paper examines the role of free association from the point of view of psychoanalysis and neuroscience in order to improve our understanding of therapeutic effects induced by psychoanalytic therapies and psychoanalysis. In this regard, we first propose a global overview (...) of the historical origins of the concept of free association in psychoanalysis and examine how Freud established its principles. Then, from Freud’s distinction between primary and secondary processes, we proceed to compare the psychoanalytic model with research originating from cognitive psychology and neuroscience. The notions of entropy and free energy appear particularly relevant at the intersection of these different domains. Finally, we propose the notion of symbolizing transmodality to describe certain specificities of symbolization processes within free association and we summarize the main functions of free association in psychoanalytic practices. (shrink)

The paper tries to demonstrate that the process of the increase of entropy does not explain the asymmetry of time itself because it is unable to account for its fundamental asymmetries, that is, the asymmetry of traces (we have traces of the past and no traces of the future), the asymmetry of causation (we have an impact on future events with no possibility of having an impact on the past), and the asymmetry between the fixed past and the open (...) future, To this end, the approaches of Boltzmann, Reichenbach (and his followers), and Albert are analysed. It is argued that we should look for alternative approaches instead of this, namely we should consider a temporally asymmetrical physical theory or seek a source of the asymmetry of time in metaphysics. This second approach may even turn out to be complementary if only we accept that metaphysics can complement scientific research programmes. (shrink)

The present paper is a survey of the economics of survival, a branch of ecological economics that stresses the preservation of the opportunities of future generations over an extended time horizon. It outlines the main analytical foundation of the branch - in which the concept of entropy is a major building block -, and its analysis of the interaction between the economic system and the environment. Regarding its outlook of the future, we see that the founders of the branch (...) were mainly concerned with the consequences of a serious depletion of natural resources - particularly the energetic capital of the earth. More recently, however, emphasis is being placed on problems that stem from the fragility of the global ecosystem in face of the disturbances caused by the entropic acceleration imposed by mankind. It is feared that the ongoing expansion of the scale of the economy may bring about irreversible damages to vital environmental functions, such as protection against undesirable consequences of solar radiation, maintenance of temperature within a range that will support life, and preservation of ecosystem resiliency. (shrink)

The idea that the changing entropy of a system is relevant to explaining why we know more about the system's past than about its future has been criticized on several fronts. This paper assesses the criticisms and clarifies the epistemology of the inference problem. It deploys a Markov process model to investigate the relationship between entropy and temporally asymmetric inference.

Michel Serres’s philosophy of entropy takes what he famously calls the ‘Northwest Passage’ between the sciences and the humanities. By contextualizing his approach to entropy and affirming the role of a philosophy of difference, this paper explores Serres’s approach by means of ‘entropic differences’. It claims that entropy – or rather, entropies – provide Serres with a paradigmatic case for critical translations between different domains of knowledge. From his early Hermès series, through to The Birth of Physics (...) and later writings on social and ethical themes, he keeps thermodynamical and informational – or ‘hard’ and ‘soft’ – understandings of entropy apart, while simultaneously exploring their relation. By focusing on the systematic significance of Serres’s ‘entropic difference’, this paper shows how it unfolds not necessarily as an ontological difference but as an operative function between the history and philosophy of science, epistemology, and a theory of negentropic (inter)subjectivity. (shrink)

This essay is an attempt to reconcile the disturbing contradiction between the striving for order in nature and in man and the principle of entropy implicit in the second law of thermodynamics - between the tendency toward greater organization and the general trend of the material universe toward death and disorder.

A remarkable thesis prevails in the physics of information, saying that the logical properties of operations that are carried out by computers determine their physical properties. More specifically, it says that logically irreversible operations are dissipative by klog2 per bit of lost information. (A function is logically irreversible if its input cannot be recovered from its output. An operation is dissipative if it turns useful forms of energy into useless ones, such as heat energy.) This is Landauer's dissipation thesis, hereafter (...) LDT. LDT underlies and motivates numerous researches in physics and computer science. Nevertheless, this paper shows that is it plainly wrong. This conclusion is based on a detailed study of LDT in terms of the various notions of entropy used in main stream statistical mechanics. It is supported by a counter example for LDT. Further support is found in an analysis of the phase space representation on which LDT relies. This analysis emphasises the constraints placed on the choice of probability distribution by the fact that it has to be the basis for calculating phase averages corresponding to thermodynamic properties of individual systems. An alternative representation is offered, in which logical irreversibility has nothing to do with dissipation. The strong connection between logic and physics, that LDT implies, is thereby broken off. (shrink)

I assess the thesis that counterfactual asymmetries are explained by an asymmetry of the global entropy at the temporal boundaries of the universe, by developing a method of evaluating counterfactuals that includes, as a background assumption, the low entropy of the early universe. The resulting theory attempts to vindicate the common practice of holding the past mostly fixed under counterfactual supposition while at the same time allowing the counterfactual's antecedent to obtain by a natural physical development. Although the (...) theory has some success in evaluating a wide variety of ordinary counterfactuals, it fails as an explanation of counterfactual asymmetry. (shrink)

Conventional wisdom holds that the von Neumann entropy corresponds to thermodynamic entropy, but Hemmo and Shenker (2006) have recently argued against this view by attacking von Neumann's (1955) argument. I argue that Hemmo and Shenker's arguments fail due to several misunderstandings: about statistical-mechanical and thermodynamic domains of applicability, about the nature of mixed states, and about the role of approximations in physics. As a result, their arguments fail in all cases: in the single-particle case, the finite particles case, (...) and the infinite particles case. (shrink)

This essay is an attempt to reconcile the disturbing contradiction between the striving for order in nature and in man and the principle of entropy implicit in the second law of thermodynamics - between the tendency toward greater organization and the general trend of the material universe toward death and disorder.

Although the laws of thermodynamics are well established for black hole horizons, much less has been said in the literature to support the extension of these laws to more general settings such as an asymptotic de Sitter horizon or a Rindler horizon (the event horizon of an asymptotic uniformly accelerated observer). In the present paper we review the results that have been previously established and argue that the laws of black hole thermodynamics, as well as their underlying statistical mechanical content, (...) extend quite generally to what we call here “causal horizons.” The root of this generalization is the local notion of horizon entropy density. (shrink)

Integrating concepts of maintenance and of origins is essential to explaining biological diversity. The unified theory of evolution attempts to find a common theme linking production rules inherent in biological systems, explaining the origin of biological order as a manifestation of the flow of energy and the flow of information on various spatial and temporal scales, with the recognition that natural selection is an evolutionarily relevant process. Biological systems persist in space and time by transfor ming energy from one state (...) to another in a manner that generates structures which allows the system to continue to persist. Two classes of energetic transformations allow this; heat-generating transformations, resulting in a net loss of energy from the system, and conservative transformations, changing unusable energy into states that can be stored and used subsequently. All conservative transformations in biological systems are coupled with heat-generating transformations; hence, inherent biological production, or genealogical proesses, is positively entropic. There is a self-organizing phenomenology common to genealogical phenomena, which imparts an arrow of time to biological systems. Natural selection, which by itself is time-reversible, contributes to the organization of the self-organized genealogical trajectories. The interplay of genealogical (diversity-promoting) and selective (diversity-limiting) processes produces biological order to which the primary contribution is genealogical history. Dynamic changes occuring on times scales shorter than speciation rates are microevolutionary; those occuring on time scales longer than speciation rates are macroevolutionary. Macroevolutionary processes are neither redicible to, nor autonomous from, microevolutionary processes. (shrink)

Cross entropy measure is one of the best way to calculate the divergence of any variable from the priori one variable. We define a new cross entropy measure under interval neutrosophic set environment.

In a previous paper a theory of program size formally identical to information theory was developed. The entropy of an individual finite object was defined to be the size in bits of the smallest program for calculating it. It was shown that this is − log2 of the probability that the object is obtained by means of a program whose successive bits are chosen by flipping an unbiased coin. Here a theory of the entropy of recursively enumerable sets (...) of objects is proposed which includes the previous theory as the special case of sets having a single element. The primary concept in the generalized theory is the probability that a computing machine enumerates a given set when its program is manufactured by coin flipping. The entropy of a set is defined to be − log2 of this probability. (shrink)

We investigate uncertain reasoning with quantified sentences of the predicate calculus treated as the limiting case of maximum entropy inference applied to finite domains.

A recent study suggests that value and quantum states seem to be governed by the same underlying mechanisms. In our recent book titled "Better economics for the Earth: A lesson from quantum and information theories," specifically Chapter 5, we have proposed an informational entropy-based notion of value, drawing on the granular worldview and primary features of quantum mechanics, Shannon’s information theory, and the mindsponge theory. Specifically, the notion suggests that values are created through the interactions of information. But how (...) do information and its interactions lead to values? This research note aims to contribute to the answer to this question. (shrink)

The conception of entropy came from the theoretical study of the steam-engine, and, neglecting refinements of mathematical treatment, can easily be illustrated. The motive power of the engine comes from the transformation of the heat generated by the combustion of the fuel. The mechanism transforms the kinetic energy of the molecules of heated steam into the kinetic energy of the parts of the engine. Consider a steamship under way: for a brief period of time this can be regarded as (...) an automatic physical system. Some of the heat conveyed by the steam transforms directly into mechanical energy and some passes out into the ocean in the condenser water. We take the latter fraction: in the boiler there is a certain quantity, Q 1 , at a temperature of, say, 200°C, that is, 473° absolute, and its entropy is simply Q 1 /473° ab. The same quantity passes out into the ocean where its temperature falls to, say, 10°C, or 283° ab., and its entropy is now Q 1 /283° ab. Plainly the former quantity of entropy is less than the latter, so that in the transformation of heat into mechanical energy entropy has increased . The conception has been generalized so as to include all forms of energy and all physical transformations, and it can be shown that in all physical events that occur of themselves entropy increases. The conception includes these notions: Available and unavailable energy; greater or lesser improbability of the elements of the systems contemplated; and the physical meanings of before and after. (shrink)

The Madelung equations map the non-relativistic time-dependent Schrödinger equation into hydrodynamic equations of a virtual fluid. While the von Neumann entropy remains constant, we demonstrate that an increase of the Shannon entropy, associated with this Madelung fluid, is proportional to the expectation value of its velocity divergence. Hence, the Shannon entropy may grow due to an expansion of the Madelung fluid. These effects result from the interference between solutions of the Schrödinger equation. Growth of the Shannon (...) class='Hi'>entropy due to expansion is common in diffusive processes. However, in the latter the process is irreversible while the processes in the Madelung fluid are always reversible. The relations between interference, compressibility and variation of the Shannon entropy are then examined in several simple examples. Furthermore, we demonstrate that for classical diffusive processes, the “force” accelerating diffusion has the form of the positive gradient of the quantum Bohm potential. Expressing then the diffusion coefficient in terms of the Planck constant reveals the lower bound given by the Heisenberg uncertainty principle in terms of the product between the gas mean free path and the Brownian momentum. (shrink)

A probability distribution can be given to the set of isomorphism classes of models with universe {1, ..., n} of a sentence in first-order logic. We study the entropy of this distribution and derive a result from the 0–1 law for first-order sentences.

Neural complexity and brain entropy have gained greater interest in recent years. The dynamics of neural signals and their relations with information processing continue to be investigated through different measures in a variety of noteworthy studies. The BEN of spontaneous neural activity decreases during states of reduced consciousness. This evidence has been showed in primary consciousness states, such as psychedelic states, under the name of “the entropic brain hypothesis.” In this manuscript we propose an extension of this hypothesis to (...) physiological and pathological aging. We review this particular facet of the complexity of the brain, mentioning studies that have investigated BEN in primary consciousness states, and extending this view to the field of neuroaging with a focus on resting-state functional Magnetic Resonance Imaging. We first introduce historic and conceptual ideas about entropy and neural complexity, treating the mindbrain as a complex nonlinear dynamic adaptive system, in light of the free energy principle. Then, we review the studies in this field, analyzing the idea that the aim of the neurocognitive system is to maintain a dynamic state of balance between order and chaos, both in terms of dynamics of neural signals and functional connectivity. In our exploration we will review studies both on acute psychedelic states and more chronic psychotic states and traits, such as those in schizophrenia, in order to show the increase of entropy in those states. Then we extend our exploration to physiological and pathological aging, where BEN is reduced. Finally, we propose an interpretation of these results, defining a general trend of BEN in primary states and cognitive aging. (shrink)

It has been shown by several authors that in operations involving information a quantity appears which is the negative of the quantity usually defined as entropy in similar situations. This quantity ℜ = − KI has been termed “negentropy” and it has been shown that the negentropy of information and the physical entropy S are mirrorlike representations of the same train of events. In physical terminology the energy is degraded by an increase in entropy due to an (...) increased randomness in the positions or velocities of components, wave functions, complexions in phase space; in informational terminology some information about the same components has been lost or the negentropy has been decreased. In equilibrium the system has for a given energy content maximum randomness. One consequence of this dual aspect was the idea to apply the methods of statistical mechanics to problems of communication and Brillouin showed that Fermi-Dirac statistics or generalized Fermi statistics are applicable for example to a transmission of signals such as telegrams. (shrink)

This paper explores a possible relationship between entropy and evil in terms of metaphor. After presenting the various meanings of entropy in classical thermodynamics and statical mechanics, and the Augustinian and Irenaean theodicies, several similarities and dissimilarities between entropy and evil are described. Underlying the concepts of evil and entropy is the assumption that time has a direction. After examining the scientific basis for this assumption, it is hypothesized that, if evil is real in nature, (...) class='Hi'>entropy is what one would expect to find at the level of physical processes, and conversely that, if entropy is coupled to a physical arrow of time, one could expect to find dissipative yet catalytic processes in history and religious experience. (shrink)

I discuss the statistical mechanics of gravitating systems and in particular its cosmological implications, and argue that many conventional views on this subject in the foundations of statistical mechanics embody significant confusion; I attempt to provide a clearer and more accurate account. In particular, I observe that (i) the role of gravity in entropy calculations must be distinguished from the entropy of gravity, that (ii) although gravitational collapse is entropy-increasing, this is not usually because the collapsing matter (...) itself increases in entropy, and that (iii) the Second Law of thermodynamics does not owe its validity to the statistical mechanics of gravitational collapse. (shrink)

The language of entropy is examined for consistency with its mathematics and physics, and for its efficacy as a guide to what entropy means. Do common descriptors such as disorder, missing information, and multiplicity help or hinder understanding? Can the language of entropy be helpful in cases where entropy is not well defined? We argue in favor of the descriptor spreading, which entails space, time, and energy in a fundamental way. This includes spreading of energy spatially (...) during processes and temporal spreading over accessible microstates states in thermodynamic equilibrium. Various examples illustrate the value of the spreading metaphor. To provide further support for this metaphor’s utility, it is shown how a set of reasonable spreading properties can be used to derive the entropy function. A main conclusion is that it is appropriate to view entropy’s symbol S as shorthand for spreading. (shrink)

In the sixth section of his light quantum paper of 1905, Einstein presented the miraculous argument, as I shall call it. Pointing out an analogy with ideal gases and dilute solutions, he showed that the macroscopic, thermodynamic properties of high frequency heat radiation carry a distinctive signature of finitely many, spatially localized, independent components and so inferred that it consists of quanta. I describe how Einstein’s other statistical papers of 1905 had already developed and exploited the idea that the ideal (...) gas law is another macroscopic signature of finitely many, spatially localized, independent components and that these papers in turn drew on his first two, “worthless” papers of 1901 and 1902 on intermolecular forces. However, while the ideal gas law was a secure signature of independence, it was harder to use as an indicator that there are finitely many components and that they are spatially localized. Further, since his analysis of the ideal gas law depended on the assumption that the number of components was fixed, its use was precluded for heat radiation, whose component quanta vary in number in most processes. So Einstein needed and found another, more powerful signature of discreteness applicable to heat radiation and which indicated all these properties. It used one of the few processes, volume fluctuation, in which heat radiation does not alter the number of quanta. (shrink)

I will argue, pace a great many of my contemporaries, that there's something right about Boltzmann's attempt to ground the second law of thermodynamics in a suitably amended deterministic time-reversal invariant classical dynamics, and that in order to appreciate what's right about (what was at least at one time) Boltzmann's explanatory project, one has to fully apprehend the nature of microphysical causal structure, time-reversal invariance, and the relationship between Boltzmann entropy and the work of Rudolf Clausius.

It is a fundamental cornerstone of thermodynamics that entropy (SU,V\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$S_{U,V}$$\end{document}) increases in spontaneous processes in isolated systems (often called closed or thermally closed systems when the transfer of energy as work is considered to be negligible) and achieves a maximum when the system reaches equilibrium. But with a different sign convention entropy could just as well be said to decrease to a minimum in spontaneous constant U, V processes. It (...) would then change in the same direction as the thermodynamic potentials in spontaneous processes. This article discusses but does not advocate such a change. (shrink)

A new way of understanding entropy as a macroscopic property is presented. This is based on the fact that heat flows from a hot body to a cold one even when the hot one is smaller and has less energy. A quantity that determines the direction of flow is shown to be the increment of heat gained divided by the absolute temperature. The same quantity is shown to determine the direction of other processes taking place in isolated systems provided (...) that q is determined by the state of the system. Entropy emerges as the potent energy of a system [Σ], the potency being determined by 1/T. This is shown to tie in with the statistical mechanical interpretation of entropy. The treatment is shorter than the traditional one based on heat engines. (shrink)

In theories of gravity with a positive cosmological constant, we consider product solutions with flux, of the form (A)dS p ×S q . Most solutions are shown to be perturbatively unstable, including all uncharged dS p ×S q spacetimes. For dimensions greater than four, the stable class includes universes whose entropy exceeds that of de Sitter space, in violation of the conjectured “N-bound.” Hence, if quantum gravity theories with finite-dimensional Hilbert space exist, the specification of a positive cosmological constant (...) will not suffice to characterize the class of spacetimes they describe. (shrink)