In this paper we study the set of MV-algebras with given prime spectrum and we introduce the class of spectral MV-algebras. An MV-algebra is spectral if it is generated by the union of all its prime ideals (or proper ideals, or principal ideals, or maximal ideals). Among spectral MV-algebras, special attention is devoted to bipartite MV-algebras. An MV-algebra is bipartite if it admits an homomorphism onto the MV-algebra of two elements. We prove that both bipartite MV-algebras and spectral MV-algebras can (...) be finitely axiomatized in first order logic. We also prove that there is only, up to isomorphism, a set of MV-algebras with given prime spectrum. A further part of the paper is devoted to some relations between bipartite MV-algebras and their states. Recall that a state on an MV-algebra is a generalization of a probability measure on a Boolean algebra. Particular states are the states with Bayes’ property. We show that an MV-algebra admits a state with the Bayes’ property if and only if it is bipartite. (shrink)