Inorganic-organic hybrids derived from oxovanadium sulfate motifs: Synthesis and characterization of [V IV O]∞

Abstract

The hydrothermal reaction of V2O5, V2O3, 2,2′-bpy and Na2SO4 in dilute sulfuric acid yields a novel hybrid, [VIVO]∞, which demonstrates the potential of constructing a new class of robust composite solids composed of a {V/O/SO4}-based framework decorated with organic functionalities by combining appropriate vanadyl sulfate motifs with a variety of organic ligands.

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